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lithium sulfate

CAS number
10102-25-7
Molecular weight
Molecular formula / chemical symbol
LiSO4·H2O

Description

Lithium sulfate is soluble in water, though it does not follow the usual trend of solubility versus temperature — its solubility in water decreases with increasing temperature, as its dissolution is an endothermic process. This property is shared with few inorganic compounds, such as the lanthanoid sulfates.

Lithium sulfate crystals, being piezoelectric, are also used in ultrasound-type non-destructive testing because they are very efficient sound generators. However, they do suffer in this application because of their water solubility.

Lithium sulfate

IUPAC name[hide]

Lithium sulfate

Other names[hide]

Lithium sulphate

Identifiers

CAS number

10377-48-7 Y, 
10102-25-7 (monohydrate)

PubChem

66320

RTECS number

OJ6419000

Properties[1]

Molecular formula

Li2SO4

Molar mass

109.94 g/mol

Appearance

White crystalline solid, hygroscopic

Density

2.221 g/cm3 (anhydrous)
2.06 g/cm3 (monohydrate)

Melting point

859 °C

Boiling point

1377 °C

Solubility in water

monohydrate:
34.9 g/100 mL (25 °C)
29.2 g/100 mL (100 °C)

Solubility

insoluble in absolute ethanol, acetone and pyridine

Refractive index (nD)

1.465 (β-form)

Thermochemistry

Std enthalpy of
formation
 ΔfHo298

?1436.37 kJ/mol

Specific heat capacity, C

1.07 J/g K

Hazards

EU Index

Not listed

Related compounds

Other cations

Sodium sulfate
Potassium sulfate

 Y (verify) (what is: Y/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

USES

Used as the raw material of special high-strength glass. Analytical reagent. Pharmaceutical industry


Keyword:Biological medicine food



Report

Product name

Lithium sulfate monohydrate

CAS:10102-25-7

Description

White crystalline solid, hygroscopic

TEST ITEMS

TEST RESULTS

LiSO4·H2O

≥98.0%

≥99.0%

≥99.9%

Water insoluble matter

≤0.02%

≤0.01%

≤0.01%

Free acid (H2SO4))

≤0.02%

≤0.01%

≤0.01%

Free base ( Li2CO3)

≤0.01%

≤0.007%

≤0.005%

Cl

≤0.01%

≤0.005%

≤0.002%

( PO4 )

≤0.002%

≤0.001%

---

Na

≤0.1%

≤0.05%

≤0.01%

K

≤0.05%

≤0.05%

≤0.01%

Ca

≤0.05%

≤0.03%

≤0.01%

Mg

≤0.01%

≤0.005%

≤0.001%

Fe

≤0.002%

≤0.005%

≤0.001%

Pb

≤0.002%

≤0.001%

≤0.001%