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Cesium fluoride

Cesium fluoride
Số CAS
13400-13-0
Khối lượng phân tử
151.9
Công thức phân tử / ký hiệu hóa học
CsF

Mô tả

Caesium fluoride (cesium fluoride in North America), is an inorganic compound usually encountered as a hygroscopic white solid. It is used in organic synthesis as a source of the fluoride anion. Caesium has the lowest electronegativity of all non-radioactive elements and fluorine has the highest electronegativity of all elements.

Caesium fluoride is prepared by the action of hydrofluoric acid on caesium hydroxide or caesium carbonate, followed by removal of water.

It is more soluble than sodium fluoride or potassium fluoride. It is available in anhydrous form, and if water has been absorbed it is easy to dry by heating at 100 °C for two hours in vacuo.

CsF reaches a vapor pressure of 1 kilopascal at 825 °C, 10 kPa at 999 °C, and 100 kPa at 1249 °C.

Caesium fluoride

IUPAC name[hide]

Caesium fluoride

Other names[hide]

Cesium fluoride

Identifiers

CAS number

13400-13-0 YesY

ChemSpider

24179 YesY

RTECS number

FK9650000

Jmol-3D images

Image 1

Properties

Molecular formula

CsF

Molar mass

151.90 g/mol

Appearance

white crystalline solid

Density

4.115 g/cm3

Melting point

682 °C (955 K)

Boiling point

1251 °C (1524 K)

Solubility in water

367 g/100 ml (18 °C)

Structure

Crystal structure

cubic, cF8

Space group

Fm3m, No. 225

Coordination
geometry

Octahedral

Dipole moment

7.9 D

Hazards

MSDS

External MSDS

EU Index

Not listed

Flash point

Non-flammable

Related compounds

Other anions

Caesium chloride
Caesium bromide
Caesium iodide
Caesium astatide

Other cations

Lithium fluoride
Sodium fluoride
Potassium fluoride
Rubidium fluoride

 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

ỨNG DỤNG

Analysis reagents and manufacturing of the optical crystal

Phiếu kiểm nghiệm

Product name

Cesium fluoride

CAS:13400-13-0

Description

white crystalline solid

TEST ITEMS

TEST RESULTS

CsF

≥99.5%

Ca

≤0.002%

K

≤0.04%

Al

≤0.001%

Pb

≤0.05%

Ba

≤0.01%

SO42-

≤0.05%

Cl

≤0.03%

Br

≤0.03%