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Ammonium metavanadate

 Ammonium metavanadate
Số CAS
7803-55-6
Khối lượng phân tử
116.98
Công thức phân tử / ký hiệu hóa học
NH4VO3

Mô tả

acid that acts as an insulin mimic. It functions as a catalyst in certain reactions and is known to have toxic effects in certain species. It has been found in slags and fly ash from coal burning which has been known to cause respiratory problems. Ammonium metavanadate belongs to the family of vanadates that contains many different oxidative states that are dependent on pH. Ammonium metavanadate is the most common laboratory vanadate reagent, along with potassium metavanadate, KVO3.

Crystalline ammonium metavanadate contains infinitely long chains of corner-sharing VO4 tetrahedra.

Ammonium vanadate

IUPAC name[hide]

Ammonium trioxovanadate(V)

Other names[hide]

Ammonium vanadate

Identifiers

CAS number

7803-55-6 YesY

ChemSpider

19968892 YesY

UNII

FL85PX638G YesY

RTECS number

YWD875000

Jmol-3D images

Image 1

SMILES

[show]

·                                 [NH4+].O=[V-](=O)=O

InChI

[show]

·InChI=1S/H3N.3O.V/h1H3;;;;/q;;;;-1/p+1 YesY
Key: UXJVWJGDHIZPLD-UHFFFAOYSA-O YesY

---

InChI=1/H3N.3O.V/h1H3;;;;/q;;;;- 1/p+1/rH3N.O3V/c;1-4(2)3/h1H3;/q;-1/p+1
Key: UXJVWJGDHIZPLD-KKTKNITLAZ

Properties

Molecular formula

NH4VO3

Molar mass

116.98 g/mol

Appearance

slightly yellow crystalline solid, hygroscopic

Density

2.326 g/cm3

Melting point

200 °C (473 K)

Boiling point

Decomposes

Solubility in water

0.48 g/100 ml (20°C)
0.84 g/100ml (30°C)
1.32 g/100ml (40°C)
2.42 g/100ml (60°C)
7.0 g/100 mL (100 °C)

Solubility

insoluble in ether, NH4Cl, alcohol
soluble in diethanolamine

Hazards

EU Index

Not listed

Main hazards

possible mutagen, dangerous for the environment

Flash point

Non-flammable

LD50

58.1 mg/kg, oral (rat)

Related compounds

Other anions

Ammonium orthovanadate
Ammonium hexavanadate

Other cations

Sodium metavanadate
Potassium metavanadate

Related compounds

Vanadium pentoxide

 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

ỨNG DỤNG

As chemical reagents, catalysts, driers, mordant. The ceramic industry is widely used as a glaze. Can also be used for the preparation of vanadium pentoxide.

Keywords:Fine ceramics

Phiếu kiểm nghiệm

Product name

Ammonium metavanadate

CAS:7803-55-6

Description

slightly yellow crystalline solid

Formula

NH4VO3

TEST ITEMS

TEST RESULTS

Electronic special

Chemically pure

Analytical grade

NH4VO3

≥99.5

≥98.0

≥99.0

Chloride(Cl)

≤0.001%

≤0.05%

≤0.005%

Sulfate(SO4)

≤0.005%

≤0.02%

≤0.01%

Carbonate(CO3)

Qualified

Qualified

Qualified

Fe

≤0.001%

≤0.01%

≤0.005%

Heavy metal(Pb)

≤0.001%

Ammonia solubility test

Qualified

Qualified

Qualified